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The battery and charging infrastructure technology of electric and hybrid electric vehicles offers new challenges in consumer safety and lifetime performance expectations. These new vehicles face one looming obstacle—maintaining thermal stability and preventing thermal runaways. Polymer flame retardants are crucial in EV lithium-ion battery technology. The St. Louis Group portfolio of flame retardants safely allows these battery and vehicle components to charge and operate with the reassurance of flame protection.
Polymers have contributed to significant growth in automotive innovation in consumer safety, fuel economy, and overall comfort. New polymer innovations allow electric cars to maintain lightweight efficiency and incorporate flame-retardant materials. EVs, HEVs, and PHEVs must adhere to regulatory bodies such as the United States Federal Motor Vehicle Safety Standards (FMVSS) regarding fire-retardant components. US manufacturers must adhere to these standards to reduce deaths and injuries concerning burning resistance in EV applications. Before the electric vehicle revolution, the FMVSS focused on combustible engine materials such as fuel, greases, lubricants, and interior materials regarding propagation standards. The FMVSS 302 flammability tests require that a burning rate cannot exceed 100 mm per minute, which does not consider the new challenges of EV batteries.
Electric fires are becoming increasingly common, especially in newer automotive vehicles while parked. Thermal runaway is the most significant concern to manufacturers, regulatory organizations, and consumers. With the increasing temperature in the electric powertrain and engine, that energy can further increase the temperature of the EV battery. Once an EV battery cell reaches a specific temperature, it creates a chain reaction from the unstable chemicals turning into gas. This gas form might not be able to escape the lithium-ion cells, causing the battery to catch fire, melt, or even explode. There is a potential that a thermal runaway can ignite a blaze that stems from the battery of the vehicle. Preventing thermal runaways requires strategic design such as venting, cooling, battery management, cell arrangement, and flame-retardant additives that combat the spread of the fire.
Electric and hybrid vehicles require lightweight plastics to enhance design, manufacturability, and performance. Plastics continue to drive forward e-mobility technology, but the electric powertrain creates new safety issues to consider. High voltages and increased thermal capacity create new potential ignition sources and hazardous environments. High-performance flame retardants, like those from St. Louis Group, provide various chemical and resin compatibility to halt burning and spreading in EV plastics. Depending on the type of application (interior, exterior, or under the hood), St. Louis Group offers nonhalogenated solutions, such as intumescent, organophosphorus, and endothermic flame retardants.
Flame Retardant Applications in Electric Vehicles
Flame-retardant applications in EVs offer a wide range of protection in various vehicle materials and components. New demanding EV components require flame-retardant plastic for mechanical properties. Polymers provide durability, weatherability, UV stability, chemical resistance, and thermal performance benefits.
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FireGard® Antimony provides a synergistic effect when used with halogen-based flame retardants. FireGard® antimony is available in varying particle sizes and purity levels.
Grade | Chemistry | Resin Compatability |
---|---|---|
FireGard® ATO CAS No. 1309-64-4 |
General Purpose Antimony Trioxide | PP, PE, Elastomers, HIPS, ABS, PC/ABS PPE/HIPS, Polyamides, PBT |
FireGard® HP CAS No. 1309-64-4 |
High Purity Antimony Trioxide | PP, PE, Elastomers, HIPS, ABS, PC/ABS PPE/HIPS, Polyamides, PBT |
FireGard® XF CAS No. 1309-64-4 |
Extra Fine Antimony Trioxide | PP, PE, Elastomers, HIPS, ABS, PC/ABS PPE/HIPS, Polyamides, PBT |
FireGard® SA CAS No. 15432-85-6 |
Sodium Antimonate | PET engineering plastics, PA, PBT |
FireGard® LT CAS No. 1309-64-4 |
Low Tint Antimony Trioxide | Polyester, PVC, PA, Acrylics |
BroShield® brominated flame retardants offer outstanding heat-resistant performance with low loading levels for thermoplastics.
Grade | Chemistry | Resin Compatability |
---|---|---|
BroShield® 21-B | Decabromodiphenyl Ethane | HIPS, LDPE, PP, TPE, PBT, Polyamides, ABS, PC, PC/ABS |
BroShield® 45-B | Tetrabromopththalate Ester | PVC |
BroShield® 52-B | Oligomer of Tetrabromobisphenol A | PBT, PET, PBT/PET, PC, PC/ABS, ABS |
BroShield® 67-B | Ethylene Bis Tetrabromopthalimide | HIPS, ABS, PC/ABS, HIPS/PPE, TPE, PP |
BroShield® 68-B | Tetrabromobisphenol A Bis (2,3-Dibromopropyl Ether) | PP (V-2 and V-0), PE, TPE |
BroShield® 70-B | Tris(Tribromonepentyl) Phosphate (TTBP) | PP, HIPS |
FireBlend® & SmokeShield® are synergistic additives offering excellent smoke suppression properties and are a partial replacement for antimony in many thermoset and thermoplastic applications.
Grade | Chemistry | Resin Compatability |
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FireBlend® AF-100 | Zinc/Magnesium | PP, PE, Elastomers |
SmokeShield® ZB-4 | Zinc Borate | PP, PE, Elastomers |
SmokeShield® ZS | Zinc Stannate | PP, PE, Elastomers, HIPS, ABS, PC/ABS, PPE/HIPS, Polyamides, PBT |
PhosGard® phosphorus-based, halogen-free flame retardants for EV thermoplastics offer a more environment-friendly alternative to inhibit flame ignition.
Grade | Chemistry | Resin Compatability |
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PhosGard® 600 | Phosphorus/Nitrogen Complex | PBT, PET, Polyamides |
PhosGard® 700 | Phosphorus/Nitrogen Complex | PP, PE, TPE |
PhosGard® APP-MC | Ammonium Polyphosphate | PP, PE, TPE |
PhosGard® NH4 | Phosphate Ester | Flexible Polyurethane, PVC, Engineered Resins |
The St. Louis Group flame retardants and suppressants offer a wide range of compatibility with various EVs, HEVs, and PHEVs. EVs offer new challenges when it comes to thermal stability and fire safety. With high voltages in tight spaces and more cables than traditional combustion vehicles, EV components require flame retardants to keep up with fire safety regulations. Talk to an expert today about which St. Louis Group flame retardant works best for your formulation.
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